屏幕作为建筑元素的发展历程

立面和立面设计是建筑的基本要素,媒体立面是立面设计相对较新的分支领域。文章概述了媒体立面的设计与研究过程,并以六个项目为例介绍立面设计涉及的元素与子元素如何与通信技术相互结合。     

Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.     

Nickel phosphonate MOF as efficient water splitting photocatalyst

A novel microporous two-dimensional(2D)Ni-based phosphonate metal-organic framework(MOF;denoted as IEF-13)has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational techniques.Structure resolution by single-crystal X-ray diffraction reveals that IEF-13 crystallizes in the triclinic space group Pi having bi-octahedra nickel nodes and a photo/electroactive tritopic phosphonate ligand.Remarkably,this material exhibits coordinatively unsaturated nickel(II)sites,free-P0₃H₂and-P0₃H acidic groups,a C0₂accessible microporosity,and an exceptional thermal and chemical stability.Further,its in-deep optoelectronic characterization evidences a photoresponse suitable for photocatalysis.In this sense,the photocatalytic activity for challenging H₂generation and overall water splitting in absence of any co-catalyst using UV-Vis irradiation and simulated sunlight has been evaluated,constituting the first report for a phosphonate-MOF photocatalyst.IEF-13 is able to produce up to 2,200 fimol of H₂per gram using methanol as sacrificial agent,exhibiting stability,maintaining its crystal structure and allowing its recycling.Even more,170μmol of H₂per gram were produced using IEF-13 as photocatalyst in the absence of any co-catalyst for the overall water splitting,being this reaction limited by the 0₂reduction.The present work opens new avenues for further optimization of the photocatalytic activity in this type of multifunctional materials.     

Fire hazard in transportation infrastructure: Review,assessment, and mitigation strategies

This paper reviews the fire problem in critical transportation infrastructures such as bridges and tunnels. The magnitude of the fire problem is illustrated, and the recent increase in fire problems in bridges and tunnels is highlighted. Recent research undertaken to address fire problems in transportation structures is reviewed, as well as critical factors governing the performance of those structures. Furthermore, key strategies recommended for mitigating fire hazards in bridges and tunnels are presented, and their applicability to practical situations is demonstrated through a practical case study. Furthermore, research needs and emerging trends for enhancing the “state-of-the-art” in this area are discussed.     

Performance of insulated FRP-strengthened concrete flexural members under fire conditions

This paper presents the results of fire resistance tests on carbon fiber-reinforced polymer (CFRP) strengthened concrete flexural members, i.e., T-beams and slabs. The strengthened members were protected with fire insulation and tested under the combined effects of thermal and structural loading. The variables considered in the tests include the applied load level, extent of strengthening, and thickness of the fire insulation applied to the beams and slabs. Furthermore, a previously developed numerical model was validated against the data generated from the fire tests; subsequently, it was utilized to undertake a case study. Results from fire tests and numerical studies indicate that owing to the protection provided by the fire insulation, the insulated CFRP-strengthened beams and slabs can withstand four and three hours of standard fire exposure, respectively, under service load conditions. The insulation layer impedes the temperature rise in the member; therefore, the CFRP–concrete composite action remains active for a longer duration and the steel reinforcement temperature remains below 400°C, which in turn enhances the capacity of the beams and slabs.     

热处理对Ti-Mo-V-Nb-Al合金微观结构的影响

形状记忆合金由于其优良的超弹性和形状记忆效应而在医学上有着广泛的应用，其中由于NiTi形状记忆合金相较其它形状记忆合金具有更好的超弹性和生物相容性而得到了广泛的应用。但由于镍元素的毒性，使得开发一种生物相容性更好、无镍且具有良好力学性能的形状记忆合金成为必需。Ti-Mo-V-Nb-Al五元合金就是为此而开发的一种新型形状记忆合金。本研究用X射线衍射（XRD）、透射电子显微镜（TEM）和高分辨电子显微镜（HREM）研究了不同热处理条件对Ti-Mo-V-Nb-Al形状记忆合金微观结构的影响。     

硫酸厂主鼓风机的主要设计准则

论述现代硫酸厂主鼓风机设计时必须考虑的关键因素，通过实例讨论操作费用与投资之间的平衡关系以及对装置竞争力的影响。建议在硫酸厂严酷的操作条件下改进风机特性，提高耐磨性并采用维修友好的设计。     

Influence of Polyalkylmethacrylate VII on Boundary Film Formation,Friction,Wear and Efficiency of Lubricants

1 Influence of PAMAon Boundary Fil mFormation and Friction1.1 Experi mental methodsUltra-thin optical interferometry has been used tostudy thinlubricating fil ms for more than a decade and theexperi mental details of this technique have been reportedpreviously[1].The principle of the test setup is shown inFigure1.A polished steel ball is loaded and rolled againstthe flat surface of a glass disc that is coated with a thinsemi-reflecting chromiumlayer and a silica spacer of about500nmthickne…     

澳大利亚蒂汶海奥利弗气田古油藏潜力定量评价

砂岩岩心和钻屑中的含油流体包裹体代表了隐蔽的石油显示。含有此类包裹体的石英颗粒的数目(GOI数)反映了砂岩储层中曾经历过最大的古含油饱和度，而与现今流体相无关。含油饱和度高的样品比含油饱和度低的样品的GOI数至少高一个数量级。因此，在原始油被后期填充气取代的井中，可根据这些流体包裹体的资料确定古油柱并划分原始油一水界面。此外，若能利用详细的GOI图精确确定原始油一水界面的位置，那么就可以确定古油柱的高度并估算原始石油地质储量。奥利弗(Oliver)油气田位于澳大利亚蒂汶海(Timor)，现在含有一个178．5m的油气柱，其中气柱高164m，位于14．5m油柱之上。该油气田已填充至溢出点。奥利弗-1井的GOI图显示，在现在的气柱内古油柱的总高度曾在99-132m之间，原始石油地质储量高达2亿bbl，明显高于现在4500万bbl的储量。高达1．55亿bbl的油从奥利弗构造转移到其上倾方向的倾斜断块，从而大大改善了该断块构造的勘探远景。GOI制图法是一种储层描述新方法。它能可靠探测现在被气充填的圈闭中的古油储。在新井钻探之前，利用这些资料可以定量描述气藏及其附近未测试构造的油藏潜力。     

应用斯通利波反射与高分辨率慢度测量方法探测地层中的薄气层

探测地层中的气层是地层评价的一项重要课题，通常，气体存在于小的矿穴或薄层/由薄层组成的地层中，由于常规测井的纵向分辨率通常较低，致使它们经常被忽略，本文介绍的是使用斯通利波反射和高分辨率慢度两种测量方法对薄气层进行声学测定。与围岩地层相比，一个饱和气地层具有明显不同的流体迁移率和可压缩性，在对这种地层进行声学测井过程中，流体迁移率/可压缩性的巨大变化使我们可以测量到斯通利波反射，并且它对于地层厚度不是很敏感，因此，斯通利波反射能够用于对薄气层的探测。但是，慢度测量却是受气层厚度的探测。近年来，随着慢度分析方法的不断发展，小于0.5英尺的薄气层也能被探测到了。组合使用斯通利波和慢度测量法能够保证结果的准确度。